珠江口盆地珠一坳陷古近系高自然伽马砂岩形成机制及油气地质意义

运用放射性元素寻找油气是一种非常规油气勘探手段。近年来,在珠江口盆地珠一坳陷富烃凹陷周边古近系钻遇高自然伽马(GR)砂岩,其GR值(100~300 API)甚至大于同区泥岩的GR值(100~200 API)。为了弄清该特殊现象背后的地质意义,对珠江口盆地珠一坳陷古近系高自然伽马砂岩开展了铀(U)、钍(Th)、钾(K)等3种元素含量与GR值的相关趋势线分析,从井震特征、岩性特征及矿物成分特征等入手分析了砂岩GR值增高的主要原因及成因机制,探讨了放射性元素聚集的条件、运移通道、驱动力以及油气意义。结果表明:西江、惠州地区由U含量增高导致砂岩GR值偏高,恩平、番禺地区由K,Th含量增高导致砂岩GR值偏高;砂岩GR值增高有两大成因机制,一是地下流体带来的放射性元素离子U4+在氧化-还原面处富集后导致地层GR值偏高,这种特殊现象说明在具有连通基底大断裂旁的圈闭中,U4+的富集指示了曾经油气的存在,证实了研究区油气运移通道的有效性,对于油气藏的预测有着非常重要的指导性意义,二是地表流体带来的含放射性元素的矿物大量沉积后导致地层GR值偏高,含放射性元素矿物性质不稳定,可指示近源供给的存在,对于判断物源及沉积环境有着非常重要的意义。该研究成果为预测研究区油气成藏有利区带提供了依据。     

减水剂类型对赤泥—矿渣基地聚物注浆材料性能的影响及机理研究

针对赤泥等固体废弃物对环境危害性大且利用率低等问题,以碱激发赤泥-矿渣基地聚物注浆材料为 研究对象,研究了不同掺量的聚羧酸(PA)减水剂、醛酮缩合物(AKC)减水剂和萘系(N)减水剂对材料凝结时间、流动 性及强度等的影响,并通过 XRD、傅里叶红外光谱及 SEM 等设备对减水剂的作用机理进行研究。 结果表明:减水剂增 强了材料的流动性但降低了材料的剪切应力;N 和 PA 减水剂能缩短材料的凝结时间,但 AKC 减水剂会延长材料的凝 结时间;N 和 AKC 减水剂能提高材料的强度,但 PA 减水剂会降低材料的强度;N 减水剂对材料的综合性能提升效果 更加明显,其最优掺量为 0. 7%;减水剂对赤泥-矿渣基地聚物性能提升的作用机理主要是促进地聚合物凝胶的形成。 研究成果为拓展赤泥在工程上的使用途径和效率提供了理论指导。     

转底炉处理赤泥工艺技术

为了综合利用氧化铝冶炼产生的赤泥，探索在转底炉中直接还原赤泥、磨矿磁选获得高品位直接还原铁。通过实验室试验摸索了转底炉还原工艺参数，并在转底炉工业试验线进行了工业试验。实验室结果表明，赤泥还原后的直接还原铁(DRI)金属化率可达88.6%，磁选后的铁品位可达82.1%，磁选后的铁回收率可达88.9%。工业试验中，转底炉还原后，产品金属化率平均为69.2%，将还原后的DRI磁选获得高品位的DRI产品，磁选后DRI的铁品位为72.8%，磁选后铁回收率达到了85.2%,初步打通了在转底炉中还原赤泥、磁选的工艺路径。     

Effect of the cultivation mode on red pigments production from Monascus ruber

In submerged cultures performed in chemically defined fermentation medium containing glucose and glutamate, the growth and production of water‐soluble red pigments and citrinin by the filamentous fungus Monascus ruber were studied under various carbon/nitrogen (C/N) ratios. The specific production of the red pigments was optimal at a glucose/glutamate ratio of about 10 and then steadily decreased at higher C/N ratio. In contrast, the production of the mycotoxin increased with increased C/N with an optimum in the range of 30–45. In a fed‐batch mode, it was also found that the production of pigments was not favoured in fed‐batch mode by feeding the medium with glucose while keeping the C/N ratio lower than 10. This low production likely resulted from concurrent high accumulation of L‐malic acid that was reported to inhibit this production. In contrast, this mode of cultivation was rather favourable for the production of the mycotoxin.     

Effect of marinating ingredients on temperature-induced denaturation of hemoglobin and its relation to red blood spot formation in cooked chicken breast

Red blood spot (RBS) commonly found in cooked chicken breast has caused severe economic loss as it is perceived as a sign of undercooked product. The objectives of this study were to investigate the cause of RBS as related to common ingredients used in marination, based on both chicken breast and isolated chicken hemoglobin (Hb) models. The effect of sodium chloride (NaCl), sodium tripolyphosphate (STPP), and glucose on thermal denaturation of Hb was investigated along with the extent of RBS formation in cooked marinated chicken breast. After vacuum tumbling for 65 min and subsequent storage at 4 °C for 20 hr, STPP and glucose were not absorbed into the center of chicken breast. However, Na⁺ was absorbed after 12 hr storage. The denaturation temperature (T_d) of isolated chicken Hb decreased to 65.8 °C in the presence of 1.5 M NaCl, while that of the control was 69.4 °C. STPP at pH 9 decreased T_d of Hb to 61.4 °C. The alkaline pH induced by STPP destabilized the Hb structure. RBSs were observed at 100% incidence when cooked to core temperatures of 50 and 70 °C for 1 min. RBSs were completely eliminated at core temperature of 85 °C. The ingredients used during marination appeared to have a minimal effect on RBS formation due to their limited absorption into the chicken breast. The cooking temperature is a major factor governing RBSs, as it directly affects the denaturation of Hb.     

论四川盆地天然气勘探前景

中石油及其前身已在四川盆地从事天然气勘探开发工作50余年,截至2005年底累计探明天然气地质储量逾8400×10⁸m³,累计生产天然气超过2300×10⁸m³,年产量现已超过120×10⁸m³,已成为国内目前最大的产气区。对于该盆地进一步勘探前景如何的命题,从以下4个方面给予了论证：一是资源丰富、勘探成果持久不衰，近期仍有大发现；二是要辩证地认识盆地油气地质的复杂性，探索新规律，解放新领域；三是寻求地质认识和勘探技术进步是勘探突破的关键；四是继续以盆地两大地质体系（海相古隆起体系及陆相前陆盆地体系）和8套裂缝-孔隙性储集层（中上寒武统白云岩、石炭系白云岩、上二叠统长兴组生物礁白云岩、下三叠统飞仙关组鲕状白云岩、下三叠统嘉陵江组粒屑白云岩、中三叠统雷口坡组藻粒白云岩、上三叠统须家河组长石岩屑石英砂岩和中上侏罗统红层砂岩）为对象获取更多的天然气资源量及优质储量。据此得出结论：四川盆地天然气勘探前景是广阔的，但勘探难度会逐步加大。     

岩性指示曲线重构及其在储层预测中的应用

大牛地上古生界岩性气藏主要发育在三角洲分流河道沉积的下石盒子组、海陆交互沉积的山西组及以潮坪相沉积为主的太原组,储层是储集性能较差的致密砂岩,平均孔隙度小于10％,渗透率小于1×10-2μm2,储层单层厚度一般小于10 m,砂体横向连通性较差。由于低孔、低渗特征导致储层与围岩的波阻抗差异微弱,用地震资料进行储层预测困难。为此,针对大牛地石板太工区优质储层的岩性特征和测井响应特征进行了测井综合分析,利用对岩性粒度敏感的自然伽马曲线,以及对岩性粒度响应频率较低,且与波阻抗有较好对应关系的中子曲线重构了岩性指示曲线。岩性指示曲线不仅可以有效地识别优质砂体,划分不同岩性,为地震、测井信息结合的岩性反演建立桥梁,同时也为反演结果识别气层打下了基础。利用岩性指示曲线、波阻抗和电阻率曲线进行的地震、测井联合反演技术在石板太工区取得了较好的效果,同时,对石板太工区下石盒子组盒2段、山2段进行了储层和含气性预测,划分了有利含气区带,部署的2口开发井和1口探井有2口井见气,其中1口井获高产气流。     

吐哈盆地巴喀油田特低渗砂岩油层裂缝分布特征

巴喀油田中侏罗统砂岩属特低渗透裂缝 孔隙型储集层 ,平均渗透率为 0 .3× 10 - 3μm2 ;地下基质岩块孔隙度为7.4%,渗透率为 0 .16× 10 - 3μm2 。砂岩储集层发育的主要裂缝类型有构造层理缝、正向正交缝、斜向正交缝和羽裂等 ,裂缝宽度一般为 0 .3～ 3 .2mm ,纵向切深为 0 .1～ 0 .8m ,水平延伸长度为 0 .2～ 2 .1m。裂缝以半充填为主 ,其分布受岩性、层厚和构造位置的影响 ,纵向、横向均呈带状分布 ,被裂缝切割而成的基质岩块尺寸取决于裂缝频率 ,岩块长轴方向以北西西向为主 ,与构造轴向基本一致。图 3表 4参 8